VERSION 2 AUTHOR: Stuart Beaton National Center for Atmospheric Research P.O. Box 3000 Boulder, CO 80307-3000 303-479-1038 beaton@ucar.edu DATA SET OVERVIEW: National Center for Atmospheric Research (NCAR) Lyman Alpha Hygrometer POST variable MRLA3, recorded and output at 100 samples/second Data covers research flights RF01 (2008-07-16) to RF06 (2008-07-28) and RF08 (2008-08-01) to RF17 (2008-08-15). The instrument was located in the nose section of the CIRPAS Twin Otter. There was approximately 25 cm of 1/4" OD tubing between the inlet and the instrument. INSTRUMENT DESCRIPTION: The NCAR prototype lyman alpha hygrometer measures the water vapor number density by absorption at the hydrogen lyman alpha line (121 nm). The lyman alpha source is a Resonance Inc. RF powered lyman-alpha lamp. The detector is a Hamamatsu R6800U-26 phototube. The absorption signal is affected by lamp and amplifier drift as well as atmospheric absorption due to oxygen and carbon dioxide. Since the instrument has no internal reference its output signal is referenced to the chilled mirror dew point hygrometer, constrained by lab calibrations as much as possible. The absorption pathlength is chosen to maximize sensitivity at the anticipated scientifically important H2O mixing ratio. In this experiment, the pathlength was approximately 2.5 mm, appropriate for mixing ratios in the range of 5-15 g/kg. Specifications: Instrument output: Analog voltage for absorption, cell pressure, and cell temperature. Instrument bandwidth: 100 Hz Data sample rate: 100 samples/second recorded by Twin Otter Accuracy: Mixing ratio accuracy is expected to be approximately 0.2 g/kg for mixing ratio near 10 g/kg. Precision: RMS noise is typically 0.05 g/kg for mixing ratio near 10 g/kg. DATA COLLECTION AND PROCESSING: Three analog voltage were recorded by the Twin Otter data system at 100 samples per second with a resolution of 1 mV on 10 V full scale. The voltages correspond to the lyman alpha detector signal and the sample cell pressure and temperature. Since the hygrometer does not contain an internal reference a multi-parameter least-squares fit to the chilled-mirror calculated mixing ratio is determined for each flight. The equation for the fit includes terms for H2O absorption, atmospheric absorption (largely O2 and CO2), amplifier gain and offset, and drift due to temperature and window contamination. The water vapor absorption ceofficient was determined by post-project calibration over the range of 0.08 to 15 g/kg at ambient pressure and temperature, and was consistent before and after cleaning the optical windows. Its value was fixed in the fits. DATA FORMAT: The data file name e.g. RF01_MRLA3_100Hz.out indicates the research flight number, the variable (MRLA3) and the data rate (100Hz). Files consist of two columns of tab-delimited ASCII values. End of line character is the unix LF. The first column is the mission time in seconds with 0.01 second resolution as recorded by the Twin Otter data system and reported in the cabin data file. The second column is the derived mixing ratio in g/kg. Note that the start time given in the file header is the UTC time of the first record in the file. DATA REMARKS: Discounting periods when the mixing ratio is below 1 g/kg, or the chilled-mirror dewpoint instrument was overshooting, or the lyman-alpha hygrometer was afflicted by offset shifts (see below), the calculated lyman alpha mixing ratio is usually within 0.2 g/kg of the chilled mirror mixing ratio. There are some periods, particularly at the beginning of flights when the instrument is still warming up, that the error is larger. Also the error increases when the mixing ratio goes below 1 g/kg, at which point the lyman-alpha mixing ratio may even go negative. These erroneous values have not been removed from the data set since the variations in mixing ratio may still have scientific value even though the absolute value is in error. The RMS noise of the calculated mixing ratio is typically around 0.05 g/kg, with peak-peak value of about 0.2 g/kg. During TO10, and to a lesser extent during RF04 and flights after RF10, the output voltage showed offset jumps which translate to as much as 2 g/kg. The cause of these jumps has not been determined and they cannot be reproduced. Instrument response speed: This instrument was later deployed in the VOCALS project aboard the NCAR C-130 where it showed frequency response to near 100 Hz based on power spectral density plots. Similar plots for the POST flights could only confirm response to about 10 Hz, but they appear to be limited by the 1 mV voltage resolution of the Twin Otter data acquisition system. Examination of the data reveals regions where the mixing ratio changes by 0.5 g/kg in 0.04 seconds (4 samples) with little or no equilibration time detectable at the new value so the response speed in the Twin Otter installation is probably faster than 10 ms. During some of the sawtooth manuevers in and out of clouds there appears to be some asymmetry present. This may indicate some absorption and desorption between the inlet tubing walls and the sample airstream when the mixing ratio changes by a large amount. There may be a delay in response due to the length of tubing (~ 25 cm) between the inlet and the sample cell. This delay has not been estimated at this time. CHANGES FROM VERSION 1 The version 1 mixing ratio calculations were in error by as much as 20% since they were fit to incorrect mixing ratios calculated from the chilled-mirror measured dew point.