Readme file for Huebert Group cascade impactor chemical data: We operated 8-stage Micro-Orifice Uniform Deposit Impactors (MOUDIs) at Cape Grim during the ACE-1 project. They were connected to the 10m inlet used by several other investigators. It heated entering air to reduce the relative humidity to approximately 50%. Samples were generally changed daily, though not on a fixed schedule. Some effort was taken to coordinate sample times with meteorological changes. Sampling was continuous, whether or not baseline conditions existed. In addition to the 8 impaction stages, we also analyzed the inlet stage and a backup filter. Impaction substrates were aluminum foil, while the backup filters were Millipore FALP (polytetrafluoroethylene) with 1 micron nominal pore size. Ion chromatography was used to analyze samples for sodium, ammonium, potassium, magnesium, calcium, methanesulfonate, chloride, nitrate, and sulfate. The design flow rate for the MOUDI is 30 liters per minute. Nominal cut diameters of the MOUDI stages are: Stage 50% cut (aerodynamic diameter, microns) ---------------- inlet 15 (though the 10 m inlet efficiency is not known) 1 10. 2 5.6 3 3.2 4 1.8 5 1.0 6 0.56 7 0.32 8 0.18 filter not well defined, though very small. We assume 0.10 microns for plotting purposes only, as little mass is present below that size. Aerodynamic diameter is defined as the size of a particle with unit density (1g/ml) with the same aerodynamic behavior (Stokes number) as a sampled particle. For particles > 0.1 micron or so, this works out to approximately diameter = aerodynamic diameter / sqrt(particle density). Flow rates were not always 30 lpm, so the data file indicates corrected size cuts, determined by using cut = nominal cut * sqrt(nominal flow/actual flow). File format: The data file is ASCII text. Fields are separated with tab characters. There are two header lines. The first names each column, while the second gives units. The columns are: 1) Sample name. This is included primarily to make it clear which substrates were exposed together in the same sample. 2) Beginning day for the sample (day of year) 3) Beginning time, HHMM (local time, not UTC or station time) 4) Ending day for the sample (day of year) 5) Ending time, HHMM (local time) 6) Impactor stage (0 for inlet, 1-8, F for after-filter) 7) 50% cut size for the stage, corrected for flow rate (aerodynamic diameter, microns). As a very rough first approximation, one can assume that each stage captures all particles larger than its size cut and smaller than that of the previous stage. 8-16) Concentration of ions, reported as picomoles of ion captured on the stage per mole of sampled air. 17-18) Non-seasalt sulfate, calculated using seawater ratios of sulfate to sodium (our usual method, labeled NSS) and magnesium (may correct better for soil particles blown up from the cliff, labeled NSSMg). 19-29) Error estimates for the ion concentrations They are 95% confidence limits, based on blank variability, chromatogram baseline noise, and chromatography uncertainty. They do not include errors in the flow rate, estimated at 10%, which affect all stages equally.