TITLE: 2002-JOSSO-18 P.I.(S): Lee Cooper, Jackie Grebmeier 10515 Research Dr. Suite 100, Bldg. A Marine Biochemistry & Ecology Dept. of Ecology & Evolutionary Biology University of Tennessee, Knoxville Knoxville, TN 37932 tel: 865.974.2990 fax: 865.974.7896 email: lcooper1@utk.edu website: http://arctic.bio.utk.edu FUNDING SOURCE/GRANT NUMBER: NSF OPP0125082 DATASET OVERVIEW: This dataset contains measurements of the ratios of oxygen-18/oxygen-16 in bottle samples of seawater collected from the CTD rosette on two cruises of the United States Coast Guard Icebreaker Healy (WAGB-20), May 11 - June 6, 2002, and July 19 - August 21, 2002. Samples collected on the Healy were funded through the Shelf-Basin Interactions project, which is funded by both the National Science Foundation and the Office of Naval Research. For convenience, these data are grouped with other bottle data (e.g. nutrients, salinity, temperature, and other parameters measured during the cruise), that have been made available on the JOSS web page. Data are expressed in the standard delta notation, where d18O = (Rsample/Rstandard -1) x 1000. R= ratio of oxygen-18 to oxygen-16, standard = Vienna Standard Mean Ocean Water (V-SMOW), distributed by the International Atomic Energy Agency. Not all samples that were collected have been, or are likely to be analyzed, due to cost constraints. INSTRUMENT DESCRIPTION: Samples were collected from the rosette and stored in 8 mL vials until they were analyzed mass spectrometrically. Vials were typically filled to overflowing, capped immediately after collection with a Polyseal cap, sealed with Parafilm and stored at a cool temperature. Stable isotope mass spectrometry was accomplished using a Finnigan Delta Plus dual inlet mass spectrometer mated to an automated equilibrium system that uses the traditional carbon dioxide equilibration method (Epstein and Mayeda, 1953) for determining the stable oxygen isotope ratios of these two isotopes in natural waters. Precision was 0.04 per mille, based upon multiple analyses of an internal water sample. Accuracy to the V-SMOW international standard is based upon calibration of the internal standards to the international standards, including V-SMOW. Reference: Epstein, S. & Mayeda, T. Variation of 18O content of water from natural sources. Geochimica et Cosmochimica Acta 42, 213-224. (1953). DATA FORMAT File Names (Formats): HLY0201-JOSSBe7.txt (Tab delimited text file) HLY0201-JOSSBe7.xls (MS XL 5.0/95 file) NOTE: all of our Excel files will be saved in 5.0/95 version to increase accessibility. Naming Convention: CruiseName-"JOSS"Variable.filetype (ex. HLY0201-JOSSO-18.txt) Data Format and Layout: Ship - HLY: "Healy", USCG Icebreaker WAGB-20 Year - 02 : year, 2002 Cruise# - 01 : cruise number (either 01 or 03) for the Healy for that year Station# - sequentially numbered from begining to end of cruise Cast - the CTD cast number of that station (also found in the Notes of the Event Logs on JOSS website) SampleNo - same as Bottle Bottle - the Bottle number from the CTD rosette del O18 - the primary parameter of this file, as described above Lat., Long., Date/Time - self-explanatory Depth - bottom depth in meters CTDPRS - pressure in dbars indicates depth bottle was tripped at CTDTMP - water temp at depth of each bottle The remaining columns are, in sequence, salinity, oxygen, nitrate, nitrite, phosphate, ammonium, Haardt fluorometer voltage, photosynthetic radiation, N-star (a derived nutrient tracer), chlorophyll, and phaeopigment concentrations as obtained from the JOSS data system. Data Version Number and Date: Version 1, 5/23/03 Software Compatibility: This dataset will be posted in both Microsoft Excel 5.0/95 and as a tab-delimited text file.