NOAA R/V Ron Brown STXM-NEXAFS X-Ray Microscopy Data Authors: PI Lynn M Russell 9500 Gilman Drive MC0221 La Jolla, CA 92093 lmrussell@ucsd.edu aerosols.ucsd.edu Alternate contact: Lelia Hawkins 301 Platt Blvd Claremont, CA 91711 lelia_hawkins@hmc.edu 1.0 Data Set Overview Particles were collected over 30 min to 1 hr periods during Leg 2 of the RHB cruise onto silicon nitride windows. Samples were stored frozen and analyzed between Jan 2009 and Jan 2010 at the Advanced Light Source at the Lawrence Berkeley National Lab. Details can be found in Hawkins et al., 2010, JGR and Hawkins and Russell, 2010, Adv Met. Individual particles were measured for organic functional groups at nm resolution. Particle size and shape were also recorded. Samples were collected from 11/8/2008 to 11/30/2008. See Streaker Notes.txt for window sample times. Not all windows were analyzed to due constrained access to the LBL advanced light source. If you are interested in a specific time, contact Lynn M. Russell for the possibility for future analysis. Location can be determined from RHB lat/lon information and sample time based on user needs. 2.0 Instrument description For Russell group STXM-NEXAFS analysis see Russell et al., 2002, Takahama et al., 2007;2009, Hawkins and Russell, 2010 Adv. Met. 3.0 Data Collection and Processing Particle averaged spectra and organic functional groups are available upon request. These give detailed characteristics of individual particles but do not provide any statistically significant measurements for the VOCALS campaign. 4.0 Data format Two files are provided, one with window collection time and notes, one with particle sizes, ID, and window for each particle analyzed. Tab delimited ASCII is used. 5.0 Remarks The measurements are not regularly spaced, rather measurements are based on AMS organic levels and interesting changes in particle size/number observed on board. Only Leg 2 samples are available. 6.0 References Russell, LM, SF Maria, and SCB Myneni, Mapping organic coatings on atmospheric particles, 2002, GRL, 29(16) doi:10.1029/2002GL014874. Takahama, S, S Gilardoni, LM Russell, and AD Kilcoyne, Classification of multiple types of organic carbon composition in atmospheric particles by scanning transmission X-ray microscopy analysis, 2007, Atmos. Env. 41, 9435-9451. Takahama, S, S Liu, and LM Russell, Coatings and clusters of carboxylic acids in carbon-containing atmospheric particles from spectromicroscopy and their implications for cloud-nucleating and optical properties, 2009, JGR, 115(D01202), doi:10.1029/2009JD012622. Hawkins, LN and LM Russell, Polysaccharides, Proteins, and Phytoplankton Fragments: Four Chemically Distinct Types of Marine Primary Organic Aerosol Classified by Single Particle Spectromicroscopy, 2010, Adv Met, 612132, doi:10.1155/2010/612132. Hawkins, L. N., L. M. Russell, D. S. Covert, P. K. Quinn, and T. S. Bates, Carboxylic acids, sulfates, and organosulfates in processed continental organic aerosol over the southeast Pacific ocean during VOCALS-REx 2008, 2010, JGR, 115, D13201, doi:10.1029/2009JD013276.