Seven-stage multi-jet cascade impactors (Berner et al., 1979) sampling air at 55 ± 5% RH were used to determine the sub- and supermicron concentrations of Cl-, NO3-, SO4=, methanesulfonate (MSA-), Na+, NH4+, K+, Mg+2, and Ca+2. The RH of the sampled air stream was measured a few inches upstream from the impactor. The 50% aerodynamic cutoff diameters, D50,aero, were 0.18, 0.31, 0.55, 1.1, 2.0, 4.1, and 10 um.
The impaction stage at the inlet of the impactor was coated with silicone grease to prevent the bounce of larger particles onto the downstream stages. Tedlar films were used as the collection substrate in the impaction stage and a Millipore Fluoropore filter (1.0-um pore size) was used for the backup filter. Films were cleaned in an ultrasonic bath in 10% H2O2 for 30 min, rinsed in distilled, deionized water, and dried in an NH3- and SO2-free glove box. Filters and films were wetted with 1 mL of spectral grade methanol. An additional 5 mLs of distilled deionized water were added to the solution and the substrates were extracted by sonicating for 30 min. The extracts were analyzed by ion chromatography [Quinn et al., 1998]. All handling of the substrates was done in the glove box. Blank levels were determined by loading an impactor with substrates but not drawing any air through it.
Non-sea salt sulfate concentrations were calculated from Na+ concentrations and the ratio of sulfate to sodium in seawater.
Concentrations are reported as ug/m3 at STP (25C and 1 atm).Berner et al., Sci. Total Environ., 13, 245 - 261, 1979.
Information about the 7-stage OCEC sampling and data is available in a separate PDF document provided with this data.
Data can be downloaded in an ASCII, csv (comma separated value) format that should load directly into most spreadsheets by following the ASCII link, or in binary netCDF file format by following the netCDF link